Antioxidants
You should refresh your knowledge of lipid oxidation by visiting Prof. Mangino's FST 605 website or reading in a food chemistry book.
What kinds of things do we use to prevent lipid oxidation?
Characteristics of Antioxidants
Donate H
Typically Phenolic
SH would work
Number of donatable H's
Solubility
Vapor pressure
Flavor
Color
GRAS Antioxidants (CFR 182)
Ascorbic acid
Erythorbic acid
Ascorbyl palmitate
Thiodipropionic acid*
Butylated hydroxy anisole (BHA)*
Butylated hydroxy toluene (BHT)*
Calcium ascorbate
Dilauryl dithiopropionate*
Gum Guaiac (0.1% max)
Sodium ascorbate
Tocopherols
Max 0.02% of the fat
Antioxidants (21 CFR 172)
BHA
BHT
Ethoxyquin
4-hydroxymethyl-2,6-di-tert-butyl phenol
TBHQ
TBHP
Anoxomer
Stability Constants log K
| Ca+2 | Fe+2 | Fe+3 | Cu+2 | |
| EDTA | 10.7 | 14.3 | 25.7 | 18.8 |
| Citric acid | 3.5 | 3.2 | 11.8 | 6.1 |
| Pyro phos | 5.0 | 22 | 6.7 |